您可以指定 rowTag 作为 nt:vars :

df = spark.read.format("xml").option("rowTag","nt:vars").load("file.xml")

df.printSchema()
root
 |-- nt:var: array (nullable = true)
 |    |-- element: struct (containsNull = true)
 |    |    |-- _VALUE: string (nullable = true)
 |    |    |-- _id: string (nullable = true)
 |    |    |-- _type: string (nullable = true)

df.show(truncate=False)
+-------------------------------------------------------------------------------------------+
|nt:var                                                                                     |
+-------------------------------------------------------------------------------------------+
|[[ 89:19:00.01, 1.3.0, TimeStamp], [1.9.5.67.2, 1.3.1, OBJECT ], [AB-CD-EF, 1.3.9, STRING]]|
+-------------------------------------------------------------------------------------------+

要将值作为单独的行获取，可以分解结构数组：

df.select(F.explode('nt:var')).show(truncate=False)
+--------------------------------+
|col                             |
+--------------------------------+
|[ 89:19:00.01, 1.3.0, TimeStamp]|
|[1.9.5.67.2, 1.3.1, OBJECT ]    |
|[AB-CD-EF, 1.3.9, STRING]       |
+--------------------------------+

或者，如果您只需要值：

df.select(F.explode('nt:var._VALUE')).show()
+------------+
|         col|
+------------+
| 89:19:00.01|
|  1.9.5.67.2|
|    AB-CD-EF|
+------------+