如果要验证xml，则需要为该xml创建XSD。
在此之后，就像您所做的那样，只需要调用validate方法。

package com.journaldev.xml;

import java.io.File;
import java.io.IOException;

import javax.xml.XMLConstants;
import javax.xml.transform.stream.StreamSource;
import javax.xml.validation.Schema;
import javax.xml.validation.SchemaFactory;
import javax.xml.validation.Validator;

import org.xml.sax.SAXException;

public class XMLValidation {

    public static void main(String[] args) {

      System.out.println("EmployeeRequest.xml validates against Employee.xsd? "+validateXMLSchema("Employee.xsd", "EmployeeRequest.xml"));
      System.out.println("EmployeeResponse.xml validates against Employee.xsd? "+validateXMLSchema("Employee.xsd", "EmployeeResponse.xml"));
      System.out.println("employee.xml validates against Employee.xsd? "+validateXMLSchema("Employee.xsd", "employee.xml"));

      }

    public static boolean validateXMLSchema(String xsdPath, String xmlPath){

        try {
            SchemaFactory factory = 
                    SchemaFactory.newInstance(XMLConstants.W3C_XML_SCHEMA_NS_URI);
            Schema schema = factory.newSchema(new File(xsdPath));
            Validator validator = schema.newValidator();
            validator.validate(new StreamSource(new File(xmlPath)));
        } catch (IOException | SAXException e) {
            System.out.println("Exception: "+e.getMessage());
            return false;
        }
        return true;
    }
}

这里有一个教程：

http://www.journaldev.com/895/how-to-validate-xml-against-xsd-in-java