由于您使用Hibernate，因此可以使用org.hibernate.annotations.Check

@Entity
@Table(name = "social")
@Check(name="ONE_OFF_CONSTRAINT", 
       constraints = "(website IS NOT NULL) OR (facebook IS NOT NULL) OR (instagram IS NOT NULL)")
public class Social {

    @Column(name = "website", nullable = true)
    private String website;

    @Column(name = "facebook", nullable = true)
    private String facebook;

    @Column(name = "instagram", nullable = true)
    private String instagram;
}